Your post slightly confused me so let me setup an example:
In cells A1 through A5 I have:
bob
carl
george
rick
danny
(Yes, I purposely put danny out of alpha order.)
In cell B1 I have:
=MATCH("danny",A1:A5,0)
which returns 5 (row 5)
In cell C1 I have:
=INDEX(A1:A5,B1,1)
which returns "danny"
However, for this simple project, VLOOKUP is much easier to use.
(I do not understand what columns D, E & F were supposed to contain.)