Using the data supplied, it will require three queries to achieve what you want.
SELECT Table1.col1, Table1.col2
FROM Table1;
SELECT Table1.col1, Table1.col3
FROM Table1;
Select * from Query1
UNION ALL Select * from Query2
Order by Query1.Col1;
Once you have the third query, you run a Make Table Query to put the data into a new table.