You would have to put the following formula in cell F3:
=A3
and copy down for all your data rows.
Note that you CANNOT put a formula in one cell, and have it populate other cells (using just formulas). Formulas can only return values to the cells they are put in. They cannot "write" information to cells other than the one they are put in.
To have it do it automatically with only populating one cell would require VBA. If you are interested in seeing a VBA solution, please explain the exact logic, such as:
1. What is "triggering" it to run? More specifically, what cells are we watching to be updated to cause it to run?
2. Once it is triggered to run, what is the logic for determing exactly which column to copy from? It may be obvious if there is only one other populated column, but what if multiple columns are already populated on the worksheet?