References Sheet2 row 1 every other column as you drag down...
=INDEX(Sheet2!$1:$1,1,ROW(A1)*2-1)
Index will reference a cell within a defined range based on row\column index numbers. If the defined range is Row 1 then for example index 1, 3 of that range would be cell C3.
This part of the formula...
ROW(A1)*2-1
...simply increases the column index by 2 as you drag the formula down.
Put this formula in any cell and drag it down to see how it increments the column index number.
=ROW(A1)*2-1